Overhead: This overhead shot emphasizes the height of the buildings, and how large of a moment this is for Miles. It creates a sense of fear but also excitement for the audience, which is what Miles would be feeling at the time.
Ground Level: By placing the camera at ground level when Peter gets crushed by the claws of Green Goblin, it shows defeat and how weak he is in comparison. The audience would feel fearful, and start to realize that there is a possibility he may not win.
High Angle & Low Angle: These 2 angles are swapped during this scene, one looking up at Gwen, and one at her looking down; this visual hierarchy shows the audience how skilled Gwen is in comparison to Peter and Miles, and helps introduce her alternate character as someone strong and powerful.
Eye Level: This monumental moment is captured with an eye level shot as it really emphasizes the determination and passion Miles is feeling. As eyes are one of the key ways humans show emotion, by using this shot the audience has an instant connection with how he is feeling, and they know that this is a turning point.